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The two presidents were also set to discuss major arms and energy deals at the Kremlin.
Venezuela has been a major customer for Russian arms exports in recent years.
Russian press have reported this week that Venezuela could be about to buy up to 100 T-72 and T-90 tanks worth $500m (£300m), three diesel-powered Kilo-class submarines, as well as armoured vehicles, helicopters and missiles.
Mr Chavez arrived on Wednesday and gave a speech at Moscow’s People’s Friendship University.
Characteristically, it lasted two and a half hours and included a tirade against the United States as well as a singalong, with Mr Chavez on maracas.

They challenged the 500-year-old tradition which claims a group of teenage boys have a quality of voice that their female counterparts cannot match.
Professor David Howard, from the University of York, said a controlled experiment in which 130 people listened to boys and girls singing identical pieces of music undermined the theory.
“I believe this argument is primarily sexist. It’s got nothing to do with music,” he told the British Association’s annual science festival, in Salford, Greater Manchester.
“If you have the music the same, the rest of the choir the same, the director of music the same, the acoustic the same, and you just change the top line – you can’t tell the difference

The effects of a cold could be wiped out in just over a day using a nasal spray containing zinc, according to researchers in the US.
Drug companies have been testing the spray – which is already available in the US as a homeopathic medication – in clinical trials and found that it reduced the average length of a cold from almost ten days to 36 hours..
However, specialists investigating the common cold warned that it was too early to tell if the treatment would be genuinely useful.
The spray – known as Zicam – is being developed by Gel-Tech, a joint venture between three US companies

Toshiba is to replace about 340,000 laptop computer batteries worldwide, the third recall of faulty batteries made by Sony since mid-August.
The batteries, used in Toshiba’s Dynabook and Dynabook Satellite laptops made between March and May of this year, could lose all their power.
However, unlike Dell and Apple last month, Toshiba said there was no risk of the faulty batteries catching fire.
Toshiba said the recall would not affect its earnings

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